Using the uniwb will allow one to expose more accurately for maximum dynamic range. You want to expose to the right as much as possible so that you can have more data for the darker values in the image.
To see how much more latitude you have for example in the reds, take a picture of a red card using auto wb and then uniwb with the same exposure. You will see that you can expose more using uniwb, thus moving the histogram to the right.
When you load this in camera raw, you are applying the uniwb and the histogram you see should be the same as what you saw in the camera. You can then lower the exposure in camera raw and apply a new white balance. Even if this seems to clip the histogram, you can just lower the exposure and the data remains intact. You do not loose the actual data from the raw file. Thus you will use more bits of information for the shadows which is a good thing. This means less noise as well.
Using uniwb just allows you to get the best exposure possible, and avoids clipping since you are seeing the actual raw data contained in the raw file as opposed to a jpeg image that has had the white balance coefficients added.