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Whether or not you will notice any difference depends entirely on if the RAM is your current bottleneck. If you aren't using most of your 16GB RAM, then adding more won't make a noticeable difference. If you are maxing out your RAM (or close to it), then you will absolutely benefit from going to 32GB.
Next time you're in an editing session, open up Task Manager or any other monitoring software and check your RAM usage. If it's close to 16GB, more will very likely help. If you're only using 8 or 9 GB or whatever, it isn't going to make any difference for your usage.
Also I'm not sure about LR, but in PS you can tell the program how much RAM you are allowing it to use, so make sure that is not creating an artificial bottleneck for you.
LR is highly single-threaded aside from exporting and photo merging, so most of the time it is only using a single thread of your CPU anyway (I.e. if you're moving sliders). If you do lots of AI processing with Adobe, Topaz, DXO, etc. then a CPU/GPU upgrade is going to make a very noticeable difference there. If you are just moving sliders around in LR for the most part, you won't notice much of a difference.
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