nutek Offline Upload & Sell: Off
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If you're developing 2 versions off the same RAW file, one exposed for the highlights and one for the shadows, then you will be inherently losing quality, since one of the versions will be noisier (and whatnot) than the other.
If you want to maintain absolute quality in both highlights and shadows, then you should take double exposures, with each exposure correctly exposed for the highlight and shadow respectively.
Unless the scene dictates that only a single-exposure must be captured (e.g. fast moving clouds, long exposures, people moving, etc), I would prefer double bracketted exposures.
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