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I see what you're saying, but the sun would then not be in the right position. I've been here when the sun is low (and gotten many good shots at that time), but it's a totally different look to the light, and all the buildings end up silhouetted, rather than just the one.
Also...no lights in the tower that early...no one is at work yet then.
Nice capture of the skyline!
However, to me, it would have been better if this were taken about 30 mis - 1 hour earlier ... (I read your note about stopping on a whim ) as the sun would have been lower and there might still be lights in the tower