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Well, unless you were shooting on the planet Tatooine (the one with two suns), there is something a little off in this shot. One sun is just headed towards the horizon, and the other is directly overhead.
I think to make it look better, you could clone out the horizon sun and make it cloudy back there, so you are down to the one sun overhead. Or you could try and change the temp of the light around them to match the temp of the horizon sun....